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Amines(weak base)form salts with picric acid(t

2022-08-11 23:30:51 问答库 阅读 192 次

问题详情

Amines(weak base)form salts with picric acid(trinitrophen01),and all amine picrates exhibit an absorption maximum at 359nm with a molar absorptivity of 1.25×104L·mol-1·cm-1. A 0.200g sample of aniline,C6H 5NH2,is dissolved in 500mL water. A 25.0mLaliquot is reacted with picric acid in a 250.0mL volumetric flask and diluted to volume. A 10.0mL aliquot of this is diluted to 100mL and the absorbance read at 359nm in a 1.0cm cell. If the absorbance is 0.425,what is the percent purity of the aniline?

参考答案

k359=1.25×104L·mol-1·cm-1,b=1.0cm,A=0.425
A=kbc

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